[1]罗娅君,张琦,张新申,等.大豆黄素磷脂复合物的制备及光谱学分析[J].深圳大学学报理工版,2010,27(2):224-229.
 LUO Ya-jun,ZHANG Qi,ZHANG Xin-shen,et al.Preparation and spectrum investigation of daidzein-phospholipid complex[J].Journal of Shenzhen University Science and Engineering,2010,27(2):224-229.
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大豆黄素磷脂复合物的制备及光谱学分析()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第27卷
期数:
2010年2期
页码:
224-229
栏目:
化学与化工
出版日期:
2010-04-30

文章信息/Info

Title:
Preparation and spectrum investigation of daidzein-phospholipid complex
文章编号:
1000-2618(2010)02-0224-06
作者:
罗娅君12张琦23张新申2雷雨1
1)绵阳师范学院化学与化学工程学院,四川绵阳 621000; 2.四川大学轻纺与食品学院,成都 610065
3)西南民族大学生命科学与技术学院,成都 610041
Author(s):
LUO Ya-jun12ZHANG Qi23ZHANG Xin-shen2and LEI Yu1
1)Chemistry & Chemical Engineering College,Mianyang Normal University,Mianyang 621000,Sichuan Province,P.R.China
2)School of Light Industry and Textile and Foodstuff Engineering,Sichuan University,Chengdu 610065,P.R.China
3)College of Life Science and Technology,Southwest University for Nationalities,Chengdu 610041,P.R.China
关键词:
生物化学大豆黄素大豆卵磷脂磷脂复合物光谱分析抗氧化免疫机能细胞代谢
Keywords:
biochemistrydaidzeinphospholipidphospholipid complexaction spectrum analysisantioxidantimmune functioncellular metabolismReferences:
分类号:
Q 545;O 629.9
文献标志码:
A
摘要:
以大豆黄素与大豆卵磷脂的结合率为评价标准,分别考察反应溶剂、起始浓度、投料比例、反应时间和反应温度等对产物结合率的影响,确定复合物的最佳制备工艺:以四氢呋喃为反应溶剂,大豆黄素质量浓度为2 mg/mL,投料物质的量比为1∶1,反应时间为3 h,反应温度为50 ℃.在此最佳反应条件下,磷脂复合物结合率达94.2%.对制备出的复合物进行紫外光谱、红外光谱、差热和X-衍射等光谱学分析,结果表明,大豆黄素与磷脂形成了复合物,且复合物是不同于反应物单体及单体物理混合物的新物相.
Abstract:
The combining ratio of daidzein and phospholipid was used as the assessment standard,the concentration of reactants,the ratio of reactants,reaction time and reactive temperature in this reaction were investigated, and the condition of preparing the phospholipid complex was determined. The optimal conditions were obtained using THF as the reaction solvent,the concentration of reactants being 2 mg/mL,the ratio of daidzein to phosphlipid being 1∶1,the reactive time being 3 h, the reactive temperature being 50 ℃,and the combining ratio being 94.2%.At last,the action spectrum properties of daidzein-phospholipid complex including UV spectrum,IR spectrum,differential scanning, and X-ray diffraction spectra were assayed.The action spectrum analysis shows that the structure of daidzein-phospholipid complex is different from the reactant monomers and their physical mixture.The complex is a new product that is significantly different from those of daidzein.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2009-12-15;修回日期:2010-02-14
基金项目:国家“十一五”科技支撑计划资助项目(2006BAI06A18-15)
作者简介:罗娅君(1973-),女(汉族),四川省资中市人,绵阳师范学院副研究员.E-mail:luolaowu@126.com
更新日期/Last Update: 2010-05-08