[1]邓飞,林晓冬,何永红,等.纤维类材料的差示扫描量热定量分析(英文)[J].深圳大学学报理工版,2015,32(No.2(111-220)):121-127.[doi:10.3724/SP.J.1249.2015.02121]
 Deng Fei,Lin Xiaodong,He Yonghong,et al.Quantitative analyses of fibers by differential scanning calorimetry[J].Journal of Shenzhen University Science and Engineering,2015,32(No.2(111-220)):121-127.[doi:10.3724/SP.J.1249.2015.02121]
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纤维类材料的差示扫描量热定量分析(英文)()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第32卷
期数:
2015年No.2(111-220)
页码:
121-127
栏目:
材料科学
出版日期:
2015-03-20

文章信息/Info

Title:
Quantitative analyses of fibers by differential scanning calorimetry
文章编号:
201502002
作者:
邓飞123林晓冬2何永红1李蜀2訾润2赖仕均2曾燮榕3
1)清华大学深圳研究生院,深圳 518055
2)深圳市公安局刑事科学技术研究所,深圳 518040
3)深圳市特种功能材料重点实验室,深圳陶瓷先进技术工程实验室,深圳大学,深圳 518060
Author(s):
Deng Fei123 Lin Xiaodong2 He Yonghong1 Li Shu2 Zi Run2 Lai Shijun2 and Zeng Xierong3
1)Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, P.R.China
2) Institute of Forensic Science and Technology, Shenzhen Police Bureau, Shenzhen 518040, P.R.China
3) Shenzhen Key Laboratory of Special Functional Materials, Shenzhen Engineering Laboratory of Advanced Technology for Ceramics, Shenzhen University, Shenzhen 518060, P.R.China
关键词:
鉴定科学纤维热分析差示扫描量热熔融热红外光谱混纺纤维
Keywords:
forensic science fibers thermal analysis differential scanning calorimetry(DSC) molten heat infrared spectroscopy polyester-cotton composite fiber
分类号:
TQ 171.77+1.2
DOI:
10.3724/SP.J.1249.2015.02121
文献标志码:
A
摘要:
采用差示扫描量热(differential scanning calorimetry,DSC)技术,对10种标准纤维类样品和5种自行制备的涤纶-棉混纺纤维样品进行定性和定量分析.结果表明,DSC方法可以实现多种纤维类样品的定性分析. 涤纶-棉混合纤维样品的定量分析表明,DSC方法有望实现混纺类纤维样品的定量分析,涤纶-棉混合纤维的定量分析绝对误差小于3.0%.
Abstract:
We use differential scanning calorimetry (DSC) to examine ten pure standard fiber samples and five polyester-cotton composite fiber samples to look for fiber evidence. The results show that the characteristics of DSC curves such as typical molten peak shape and position can serve as the useful criteria for differentiating fiber samples. Quantitative analyses of polyester-cotton composite fiber samples yield precise results with absolute errors generally being less than 3.0%, which confirms the feasibility of using the DSC method for forensic identification.

参考文献/References:

[1] Marcia M L Y, Sandercock M P L. Principal component analysis and analysis of variance on the effects of entellan new on the raman spectra of fibers[J]. Journal of Forensic Sciences, 2012, 57(1): 70-74.
[2] Michael C, Andrew P, Tegan E, et al. The effect of ionizing gamma radiation on natural and synthetic fibers and its implications for the forensic examination of fiber evidence[J]. Journal of Forensic Sciences, 2011, 56(3): 591-605.
[3] Patrick B, Genevieve M. A simple solubility tests for the discrimination of acrylic and modacrylic fibers[J]. Journal of Forensic Sciences, 2013, 58(6): 1593-1600.
[4] Roberston J, Grieve M. Forensic examination of fibers[M]. London: Taylor & Francis, 2003.
[5] Ehrensttein G, Riedel G, Trawiel P. Thermal analysis of plastics[M]. Munich(Germany): Carl Hanser Verlag, 2004.
[6] Riga A. Thermal analysis as an aid to forensics: alkane melting and oxidative stability of wool[C]// The 25th North American Thermal Analysis Conference. Virginia(USA): Thermochimica Acta, 1998: 151-163.
[7] Zhao H F, Zhu Y B, Sha L Z. Study of the relationship between characteristics of aramid fibrids and mechanical property of aramid paper using DSC[J]. Polymers, 2014, 14(2): 139-144.
[8] Huang J, Manisha D. Evaluation of integrated raman-DSC technology in early pharmaceutical development:characterization of polymorphic systems[J]. Journal of Pharmaceutical and Biomedical Analysis, 2013, 86: 92-99.
[9] Mlcoch T, Kucerik J. Hydration and drying of various polysaccharides studied using DSC[J]. Journal of Thermal Analysis and Calorimetry, 2013, 113(3): 1177-1185.
[10] Mahato D N, Mathur B K, Bhattacherjee S. DSC and IR methods for determination of accessibility of cellulosic coir fibre and thermal degradation under mercerization[J]. Indian Journal of Fibre & Textile Research, 2013, 38(1): 96-100.
[11] Hassan A, Normasmira Y. Extrusion and injection-molding of glass fiber/MAPP/polypropylene: effect of coupling agent on DSC, DMA, and mechanical properties[J]. Journal of Reinforced Plastics and Composites, 2011, 30(14): 1223-1232.
[12] Fu Z J, Huang H F, Yu L S. DSC Studies on the dyeing properties of PLA fiber[C]// The 3rd International Conference on Advanced Engineering Materials and Technology. Zhangjiajie(China): Advanced Materials Research, 2013: 1393-1396.
[13] Ihms E C, Brinkman D W. Thermo gravimetric analysis as a polymer identification technique in forensic applications[J]. Journal of Forensic Sciences, 2004, 49(3): 505-510.
[14] Foldes E, Keresztury G, Iring M, et al. Crystallinity of polyethylene measured by density, DSC and Raman spectroscopy:a comparison[J]. Ange Wandte Makromolekulare Chemie, 2003, 187(1): 87-91.
[15] Sajwan M, Aggarwal S, Singh R B. Forensic characteri-zation of HDPE pipes by DSC[J]. Forensic Science International, 2008, 175(2/3): 130-133.
[16] Tsukame T, Kutszaw M, Selane H, et al. Identification of polyethylene by DSC: application to forensic science[J]. Journal of Thermal Analysis and Calorimetry, 1999, 57(3): 847-851.
[17] Ionashiro E Y, Hewer T S R, Fertonani F L, et al. Application of differential scanning calorimetry in hair samples as a possible tool in forensic science[J]. Ecletica Quimica, 2004, 29(2): 53-56.
[18] Singh D. Characterization of PET fibers by some physical methods[D]. New Delhi(India): University of Delhi, 1994.
[19] Bershtein V A, Egorov V M, Kem T J. Differential scanning calorimetry of polymers: physics, chemistry, analysis, technology[M]. Chichester(UK): Ellis Horwood, 1994.
[20] Hohne G W H, Hemminger W F, Flammersheim H J. Differential scanning calorimetry[M]. New York(USA): Springer-Verlag, 2003.

备注/Memo

备注/Memo:
基金项目:公安部重点研究计划资助项目(20102DYJGDST005);深圳市特种功能材料重点实验室和深圳陶瓷先进技术工程实验室开放基金资助项目(T201005)
作者简介:邓飞(1980—),男(汉族),河北省辛集市人,清华大学及深圳市公安局刑事科学技术研究所博士后研究人员.E-mail:fdeng80@163.com
引文:邓飞,林晓冬,何永红,等.纤维类材料的差示扫描量热定量分析[J]. 深圳大学学报理工版,2015,32(2):121-127.(英文版)
Received:2014-07-09;Revised:2014-10-16;Accepted:2015-01-31
Foundation:Key Research Project of Chinese Ministry of Public Security (20102DYJGDST005); Open Project of Shenzhen Key Laboratory of Special Functional Materials and Shenzhen Engineering Laboratory of Advanced Technology for Ceramics (T201005)
Corresponding author:Post doctor Deng Fei.E-mail: fdeng80@163.com
Citation:Deng Fei,Lin Xiaodong,He Yonghong,et al.Quantitative analyses of fibers by differential scanning calorimetry[J]. Journal of Shenzhen University Science and Engineering, 2015, 32(2): 121-127.
更新日期/Last Update: 2015-03-12