[1]倪卓,林煜豪.外援型微胶囊自修复材料的研究进展[J].深圳大学学报理工版,2017,34(No.5(441-550)):441-450.[doi:10.3724/SP.J.1249.2017.05441]
 Ni Zhuo and Lin Yuhao.Research progress of extrinsic microcapsule self-healing materials[J].Journal of Shenzhen University Science and Engineering,2017,34(No.5(441-550)):441-450.[doi:10.3724/SP.J.1249.2017.05441]
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外援型微胶囊自修复材料的研究进展()
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《深圳大学学报理工版》[ISSN:1000-2618/CN:44-1401/N]

卷:
第34卷
期数:
2017年No.5(441-550)
页码:
441-450
栏目:
化学与化工
出版日期:
2017-09-20

文章信息/Info

Title:
Research progress of extrinsic microcapsule self-healing materials
文章编号:
201705001
作者:
倪卓林煜豪
深圳大学化学与环境工程学院,广东深圳518060
Author(s):
Ni Zhuo and Lin Yuhao
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, P.R.China
关键词:
自修复材料微胶囊外援型微裂纹环戊二烯催化剂聚二甲基硅氧烷活性溶剂环氧树脂异氰酸酯
Keywords:
self-healing materials microcapsules extrinsic microcracks dicyclopentadiene catalyst polydimethylsiloxane active solvent epoxy resin isocyanate
分类号:
TQ 322
DOI:
10.3724/SP.J.1249.2017.05441
文献标志码:
A
摘要:
评述近年国内外数种外援型微胶囊自修复复合材料体系的研究成果,包括双环戊二烯-Grubbs体系、聚二甲基硅氧烷体系、活性溶剂体系、环氧树脂体系和异氰酸酯体系等,比较这些体系微胶囊的设计方法、主要性能和应用范围等.设计外援型微胶囊自修复复合材料,通过胶囊破裂流出囊芯可有效封闭裂纹,达到延长材料服役寿命的效果.指出材料断裂机理与微裂纹的产生及扩展密切相关,断裂行为决定高聚物材料中设计化学体系进行智能修复的过程.开辟了自修复聚合物材料科学研究新方法和工程应用的新途径.展望了微胶囊自修复材料的科研和工程应用前景.
Abstract:
This review briefly introduces several extrinsic microcapsule self-healing composite materials, including dicyclopentadiene-Grubbs, polydimethylsiloxane, active solvent, epoxy resin, and isocyanate chemicals. The comparisons of the self-healing designs, main performances and ranges of use on these the microcapsule materials in these systems are evaluated based on the original data. To realize the material self-healing, the extrinsic microcapsules in the self-healing composite materials are designed to be able to rupture and discharge core chemicals which can effectively adhere cracks, therefore to prolong the service life of the composites. The fracture mechanism of the materials is related to the micro-cracks generated during mechanical applications. The fracture behaviors have the influences on the intelligent healing process of the designed self-healing system. Such chemical systems of these intelligent healing materials have been developed as the new scientific method and high-tech engineering applications in the near future. This review makes some comments on the advancements of self-healing composite materials with extrinsic microcapsules, and the difficulties in the microcapsule self-healing composite materials.

参考文献/References:

[1] 李成功.新材料研究发展与产业化趋势[J].中国机械工程, 2000, 11(1): 154-156.
Li Chenggong. Research and development of advanced materials and advanced material industry advanced material industry[J]. China Mechanical Engineeging,2000,11(1):154-156.(in Chinese)
[2] May C A, Tanaka Y. Epoxy resins: chemistry and technology[J]. Dekker, 1988(5):19-20.
[3] 李兴旺,张玉奇,廖亮,等.智能型混凝土修补材料体系研究进展[J].土木建筑与环境工程, 2006, 28(4): 142-145.
Li Xingwang, Zhang Yuqi, Liao Liang, et al. Progress of intelligent concrete repair materials[J]. Journal of Civil, Architectural & Environmental Engineering, 2006, 28(4): 142-145.(in Chinese)
[4] 付晓芸. 用于聚合物基自修复材料的修复单体的合成与表征[D]. 杭州:浙江大学,2008.
Fu Xiaoyun. Synthesis and characterization of the self-healing monomers for polymer composites[D]. Hangzhou: Zhejiang University, 2008.(in Chinese)
[5] Outwater J O, Gerry D J. On the fracture energy, rehealing velocity and refracture energy of cast epoxy resin[J]. The Journal of Adhesion, 1969, 1(4): 290-298.
[6] Dry C, Corsaw M. A comparison of bending strength between adhesive and steel reinforced concrete with steel only reinforced concrete[J]. Cement and Concrete Research, 2003, 33(11): 1723-1727.
[7] White S R, Sottos N R, Geubelle P H, et al. Autonomic healing of polymer composites[J]. Nature, 2001, 409(6822): 794-797.
[8] Tziviloglou E, Tittelboom K V, Palin D, et al. Bio-based self-healing concrete: from research to field application[M]. Switzerland: Springer International Publishing, 2016.
[9] Tan N P, Keung L H, Choi W H, et al. Silica-based self-healing microcapsules for self-repair in concrete[J]. Journal of Applied Polymer Science, 2016, 133(12): 43090.
[10] Ming Yaoqiang, Hu Jianfeng, Xing Junheng, et al. Preparation of polyurea/melamine formaldehyde double-layered self-healing microcapsules and investigation on core fraction[J]. Journal of Microencapsulation, 2016, 33(4): 307-314.
[11] Sun Dawei, Zhang He, Tang Xiuzhi, et al. Water resistant reactive microcapsules for self-healing coatings in harsh environments[J]. Polymer, 2016, 91:33-40.
[12] Kardar P. Preparation of polyurethane microcapsules with different polyols component for encapsulation of isophorone diisocyanate healing agent[J]. Progress in Organic Coatings, 2015, 89: 271-276.

[13] Wang Yingyuan, Su Junfeng, Schlangen E, et al. Fabrication and characterization of self-healing microcapsules containing bituminous rejuvenator by a nano-inorganic/organic hybrid method[J]. Construction and Building Materials, 2016, 121: 471-482.
[14] Sarkar S, Kim B. Synthesis of graphene oxide-epoxy resin encapsulated urea-formaldehyde microcapsule by in situ polymerization process[J]. Polymer Composites, 2016.
[15] Yamuna J, Siva T, Kumari S, et al. A smart poly(aniline-formaldehyde) microcapsule based self-healing anticorrosive coating[J]. RSC Advances, 2016, 6(1): 79-86.
[16] Thakur V K, Kessler M R. Self-healing polymer nanocomposite materials: a review[J]. Polymer, 2015, 69: 369-383.
[17] 汪海平,容敏智,章明秋. 微胶囊填充型自修复聚合物及其复合材料[J]. 化学进展, 2010, 22(12): 2397-2407.
Wang Haiping, Rong Minzhi, Zhang Mingqiu. Self-healing polymers and polymer-based composites containing microcapsules[J]. Progress in Chemistry, 2010, 22(12): 2397-2407.(in Chinese)
[18] Brown E N, White S R, Sottos N R. Retardation and repair of fatigue cracks in a microcapsule toughened epoxy composite[J]. Composites Science and Technology, 2005, 65(15): 2466-2480.
[19] Brown E N, Sottos N R, White S R. Fracture testing of a self-healing polymer composite[J]. Experimental Mechanics, 2002, 42(4): 372-379.
[20] Brown E N, White S R, Sottos N R. Microcapsule induced toughening in a self-healing polymer composite[J]. Journal of Materials Science, 2004, 39(5): 1703-1710.
[21] Rule J D, Brown E N, Sottos N R, et al. Wax-protected catalyst microspheres for efficient self‐healing materials[J]. Advanced Materials, 2005, 17(2): 205-208.
[22] Kamphaus J M, Rule J D, Moore J S, et al. A new self-healing epoxy with Tungsten (VI) chloride catalyst[J]. Journal of the Royal Society Interface, 2008, 5(18): 95-103.
[23] Skipor A, Scheifer S, Olson B. Microcapsule containing a flowable polymerizable material, and having a polymerization agent(s) in the outer surface for inducing polymerization upon rupture of the microcapsule; electronics, packaging, sealants, coatings, tire parts[J]. Langmuir the Acs Journal of Surfaces & Colloids, 2005, 21(4):1539-1546.
[24] Cho S H, Andersson H M, White S R, et al. Polydimethylsiloxane-based self-healing materials[J]. Advanced Materials, 2006, 18(8): 997-1000.
[25] Caruso M M, Delafuente D A, Ho V, et al. Solvent-promoted self-healing epoxy materials[J]. Macromolecules, 2007, 40(25): 8830-8832.
[26] 倪卓,杜学晓,王帅,等. UF微胶囊合成反应的动力学研究[J]. 深圳大学学报理工版, 2011, 28(3):249-254.
Ni Zhuo, Du Xuexiao, Wang Shuai, et al. Kinetics of synthesis of UF microcapsules[J]. Journal of Shenzhen University Science and Engineering, 2011, 28(3): 249-254.(in Chinese)
[27] 倪卓,杜学晓.自修复环氧胶黏剂分子设计[J].高分子材料科学与工程, 2009(7): 133-136.
Ni Zhuo, Du Xuexiao. Materials design for Self-Healing epoxy adhesive[J]. Polymer Materials Science & Engineering, 2009(7): 133-136.(in Chinese)
[28] 倪卓, 杜学晓,王帅,等. 微胶囊对微胶囊/环氧树脂复合材料增韧作用[J]. 复合材料学报, 2011, 28(4):63-69
Ni Zhuo, Du Xuexiao, Wang Shuai, et al. Effects of microcapsules on toughening properties for microcapsule/epoxy composites[J]. Acta Materiae Compositae Sinica, 2011, 28(4): 63-69.( in Chinese)
[29] 倪卓,杜学晓,邢锋,等. 表面活性剂对自修复环氧树脂微胶囊的影响[J]. 深圳大学学报理工版, 2008, 25(4): 25-31.
Ni Zhuo, Du Xuexiao, Xing Feng, et al. Effects of surfactant on MUF encapsulated epoxy in self-healing[J]. Journal of Shenzhen University Science and Engineering, 2008, 25(4): 25-31.( in Chinese)
[30] 张鸣,陈令坤,邢锋,等. 用于自修复水泥基材料的微胶囊体系性能研究[J]. 建筑材料学报, 2013, 16(5): 903-907.
Zhang Ming, Chen Lingkun, Xing Feng, et al. Study on properties of microcapsule system for Self-Healing cementitious composite[J]. Journal of Building Materials, 2013, 16(5): 903-907.(in Chinese)
[31] 冯建中,明耀强,张宇帆,等. 异氰酸酯胶囊型自修复高分子材料研究进展[J]. 化工进展, 2016, 35(1): 175-181.
Feng Jianzhong, Ming Yaoqiang, Zhang Yufan, et al. Progress of research on encapsuled isocyanate self-healing polymeric materials[J]. Chemical Industry and Engineering Progress, 2016, 35(1): 175-181.(in Chinese)
[32] Yang J, Keller M W, Moore J S, et al. Microencapsulation of isocyanates for self-healing polymers[J]. Macromolecules, 2008, 41(24): 9650-9655.
[33] Credico B D, Levi M, Turri S. An efficient method for the output of new self-repairing materials through a reactive isocyanate encapsulation[J]. European Polymer Journal, 2013, 49(9): 2467-2476.
[34] Wang Wei, Xu Likun, Li Xiangbo, et al. Self-healing properties of protective coatings containing isophorone diisocyanate microcapsules on carbon steel surfaces[J]. Corrosion Science, 2014, 80(3): 528-535.
[35] Wang Wei, Xu Likun, Li Xiangbo, et al. Self-healing mechanisms of water triggered smart coating in seawater[J]. Journal of Materials Chemistry A, 2014, 2(6): 1914-1921.
[36] Huang Mingxing, Zhang He, Yang Jinglei. Synthesis of organic silane microcapsules for self-healing corrosion resistant polymer coatings[J]. Corrosion Science, 2012, 65(12):561-566.
[37] Yin Tao, Rong Minzhi, Wu Jingshen, et al. Healing of impact damage in woven glass fabric reinforced epoxy composites[J]. Composites Part A: Applied Science and Manufacturing, 2008, 39(9): 1479-1487.
[38] Jung D, Hegeman A, Sottos N R, et al. Self-healing composites using embedded microspheres[J]. Composites and Functionally Graded Materials, 1997,80: 265-275.
[39] 刘云鹏. 微胶囊型自修复聚硅氧烷弹性体的结构与性能研究[D]. 广州:华南理工大学, 2015.
Liu Yunpeng. Structure and properties of microcapsuled self-healing polysiloxane elastomer[D]. Guangzhou: South China University of Technology, 2015.(in Chinese)

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备注/Memo

备注/Memo:
Received:2017-01-05;Revised:2017-07-04;Accepted:2017-07-10
Foundation:National Natural Science Foundation of China (51378315); Scientific and Technological Research and Development Foundation of Shenzhen City(JCYJ20170302141509023)
Corresponding author:Professor Ni Zhuo. E-mail: royzhuoni@hotmail.com
Citation:Ni Zhuo, Lin Yuhao. Research progress of extrinsic microcapsule self-healing materials[J]. Journal of Shenzhen University Science and Engineering, 2017, 34(5): 441-450.(in Chinese)
基金项目:国家自然科学基金资助项目(51378315); 深圳市科学技术研究与发展基金资助项目(JCYJ20170302141509023)
作者简介:倪卓(1963—),男,深圳大学教授、博士生导师. 研究方向:生物材料和功能材料. E-mail:royzhuoni@hotmail.com
引文:倪卓,林煜豪. 外援型微胶囊自修复材料的研究进展[J]. 深圳大学学报理工版,2017,34(5):441-450.
更新日期/Last Update: 2017-09-11